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Posted by gmays 4 days ago

Glue bonds to nonstick surfaces and wipes clean with ethanol(cen.acs.org)
111 points | 49 comments
culi 8 minutes ago|
There's an endless stream of non-stick pans in Goodwills. I feel bad for the people that don't know better and buy used non-stick pans and I also feed bad about the sheer amount of waste being generated. It would be incredible if this could be used to get rid of scratched up or otherwise unsafe non-stick coatings to the point that the pan is still food safe
pastage 3 minutes ago|
AFAIK. Non-stick pans are not toxic, the material is inert unless it is in gas form (when you burn nonstick), and the production phase is horribly toxic. EDIT: I agree they are very waste full since they do not live that long. I have owned three non-stick pans, my cast iron pans have outlived all of them by decades.
culi 49 seconds ago||
Non-stick pans are fine if they are never heated above 500°F (260°C) and never scratched. In general, you probably shouldn't regularly use a nonstick pan for longer than 2 years.

If it is scratched or heated above what it says on the label, then yes it is absolutely toxic.

murderfs 3 hours ago||
> “Since ethanol is the main component of hand sanitizer, we believe it is possible to de-bond and recycle the adhesive by using hand sanitizer as a substitute in certain real-world situations,” Aida says.

These sorts of environmental impact blurbs are hilarious. What kind of scenario are they envisioning where someone wants to remove and reuse a specialized adhesive bonding PTFE parts to something, but don't have ethanol on hand and have to fall back to using hand sanitizer?

gizmo686 2 hours ago||
Who says this will be a specialized adhesive? If it works as advertised, it could be a super-glue alternative with easy unglueability. That would be an attractive consumer product; and the type of product that could easily end up on someones hands.
danbruc 23 minutes ago||
Superglue is probably two order of magnitude stronger, so I doubt that this will replace cyanoacrylates. And while ethanol or hand sanitizer will not help much with superglue, acetone or nail polish remover will remove it. Then again, acetone will attack more materials then ethanol, so a glue that can be removed with ethanol might still be beneficial.
loeg 2 hours ago|||
Hand sanitizer is also contaminated with other crap... presumably that impacts the adhesive if you're attempting to "recycle" it? I agree, what a weird line.
addaon 2 hours ago|||
One example might be ungluing a lithium pouch cell (usually polyamide film outer surface, which is a pretty low-surface-energy polymer) for home replacement. Electrically-debonded adhesives are a better option here, but not sure what the cost trade-offs look like.
kazinator 1 hour ago|||
Maybe a 2026 remake of MacGyver?
ortusdux 1 hour ago|||
Stick on nails
colechristensen 49 minutes ago||
Gelled solvents are useful for softening adhesives in certain situations far better than the pure substance
oflannabhra 3 hours ago||
I guess one of my favorite old-school websites will need to get updated, ThisToThat [0].

[0] - https://www.thistothat.com

DannyBee 3 hours ago|
This website often suggests totally bad ideas, like brittle epoxies for bonds they shouldn't be used for.

The truth is nowadays you can just choose your favorite brand and they almost certainly have a correct, and good, adhesive selector.

For example, for loctite, you should just use: https://www.henkel-adhesives-selector.com/

oflannabhra 3 hours ago||
maybe, but where is the whimsy or delight in that?
BenjiWiebe 2 hours ago||
Not a lot of whimsy and delight in having your glue joint fail because the delightful & whimsical website gave bad advice.
freediddy 1 hour ago||
I'm thankful they are researching the environmental impact of this. The last thing we need is another PFAS debacle decades later.
trollbridge 1 hour ago|
No kidding. Fluoro-anything needs to be checked out for impact on the ozone layer, problems that happens when it burns, and problems that happens when it flakes off and gets ingested by people.
ble 3 hours ago||
Interesting that it seems like the application method is to melt the glue:

> To test its adhesive strength, researchers first glued two untreated polytetrafluoroethylene (PTFE) plates by sandwiching molten CyclicFP-fmoc between them and letting it cool at room temperature for 10 min.

Also notable that the glue substance is reusable:

> Remarkably, a simple ethanol wash completely stripped CyclicFP-fmoc from the target PTFE plates, leaving no trace behind. The recovered adhesive proved repeatedly reusable, reliably maintaining its adhesive strength of ~1.2 ± 0.1 MPa across multiple cycles.

Perhaps hot glue guns are going to get an update ;)

bombela 2 hours ago|
For anybody not getting the reference, standard glue gun glue is obviously applied freshly melted and hot, and it is dissolved/debonded cleanly with isopropyl alcohol.
kazinator 1 hour ago||
But does not stick to "nonstick" surfaces, which the researchers claim this does.
mint5 2 hours ago||
Yay more sources of weird forever chemicals. And while it’s been a long time since I had ochem, there’s quite a few places this molecule looks like it can break apart.

They should show results from oxidation, thermal stability, accelerated aging tests.

And I’m beyond skeptical anyone would carefully recover this gunk each even once for re-use outside some contrived lab demo.

ssl-3 3 hours ago||
I'm very impressed that they were able to use glue on PTFE for...approximately anything at all. That's impressive.

But I'd like to take this opportunity to present my semi-annual rant about hot glue (edit: from a hot glue gun), instead.

It's amazing stuff. It's similar to many other liquid adhesives in that you can stick things together with it (probably not PTFE, but...), and they stay pretty well stuck.

But it's got this really neat property that most other things lack: When used with non-porous surfaces, it's removable. A few drops of isopropyl alcohol will eek in between the glue and the surface it is stuck to. It stays solid, but basically just falls right off with no apparent mess.

...which makes it absolutely fantastic for temporary fixturing.

Like: Glue an accelerometer to the middle of the 3D printer bed for resonance tuning using a very thin layer of hot glue, and then just use a bit of isopropyl to take it off later. It's like it never happened.

kazinator 1 hour ago||
I have an electric guitar which has an uncovered electronic cavity in the back, where the volume pot is mounted, and all wiring passing through it. I have a DPDT sliding switch there which is just held by hot glue to the side of the cavity, and recessed in a bit so that it isn't accidentally moved. It's been that way for years. From time to time it used to come off spontaneously, requiring a re-gluing, but I learned to do it better.

When redoing the wiring for one reason or another, it's trivially easy to peel the switch off with a screwdriver and remove the glue.

There isn't a compellingly better way of attaching that switch there. It has mounting screw holes but they point in the wrong direction, into the cavity. To screw it down, I would need some sort of long risers that somehow attach to the bottom of the cavity and are firm enough to resist the side to side push. Little L-brackets could work that attach to the side of the cavity. It's a very small cavity: hard to screw such brackets in, but that can be solved. Even if the brackets themselves were permanently mounted, not having to be removed when the switch is taken out, it would still take more time than with the glue.

Another use I have for glue is to secure a household internet connection. It's just a thin wire coming out of a RJ jack in the wall, in a room where kids play. The installer didn't crimp the plug into the cable insulation. The situation is that the insulation ends a few millimeters before the RJ plug, leaving a couple of bare wires that seem like 22 AWG crimped in. I "kid-proofed" this with hot glue. Hot glue is all over that plug, and about two feet of the cable is basically encased in hot glue, attached to the switch plate and along the wall right until the point it goes behind some furniture. I check on it from time to time to repair any tearing away.

bluGill 3 hours ago||
There are many different hot glues, not all have that property.
ssl-3 2 hours ago||
TIL.

Which ones have this property, and which ones do not? How do we tell them apart?

How do I identify the cheap hot glue that came with the cheap hot glue gun that I bought at Dollar General on a Saturday afternoon in 2021? It does this business just fine.

bluGill 2 hours ago|||
Not all hot glue comes in stick form for use in a glue gun. When I hear hot glue I first think of hide glue for example.
gertop 2 hours ago|||
The ones that don't have the property are expensive specialized/stronger glue sticks. If you stick to dollar general you don't have to think about it.
eszed 2 hours ago||
> it is imperative to study this molecule’s environmental fate and impact before pressing it into service.

Yes, let's do that, this time.

Sounds like a super-cool and useful molecule, but externalities can be killer.

bertjk 3 hours ago||
At the risk of asking a really dumb question: Does this only work on PTFE or other flourine-compound surfaces?
coldbrewed 3 hours ago||
IANA chemist but my guess is that it's of particular interest because PTFE surfaces are especially non-stick, and non-PTFE surfaces have good options that require less exotic chemistry.

The question I have is how long will it be till the report comes out indicating that DuPont has been dumping this product and intermediate compounds into local waterways. I give it 15 years?

tengbretson 2 hours ago||
I really want to see this tested on HDPE. A simple, reliable adhesive for polyethylene could be a game changer.
pavel_lishin 5 hours ago|
My mind immediately jumped to The Mote In God's Eye.
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