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Posted by rbanffy 1 day ago

CO2 batteries that store grid energy take off globally(spectrum.ieee.org)
361 points | 300 commentspage 2
pfdietz 1 day ago|
We don't need another few-hours storage technology. Batteries are going to clobber that. What we need is a storage technology with a duration of months. That would be truly complementary to these short term storage technologies.
1970-01-01 1 day ago||
We need anything that scales quickly, safely, and cheap. Just getting us through the duck curve would be a tremendous win for energy. https://en.wikipedia.org/wiki/Duck_curve
ViewTrick1002 1 day ago||
Batteries already solve that.

https://blog.gridstatus.io/caiso-solar-storage-spring-2025/

perlgeek 1 day ago|||
We need every approach that's viable. Batteries are part of the solution, and will be in future. But I don't see why we we should assume they're better in every way than this approach
pfdietz 1 day ago||
A principle in engineering is that for any market niche, only a few, or even one, technology persists. The others are driven to extinction as they can't compete. It's the equivalent of ecology's "one niche, one species" principle.

There are far more technologies going for the hours scale storage market than will survive. Sure, explore them. But expect most to fail to compete.

abdullahkhalids 21 hours ago|||
This is not true for batteries at all. Just take a look at [1]. Many of these battery chemistries are in wide use. Batteries have several performance metrics: total storage, peak/avg power, round-trip efficiency, lifetime, capex, opex,etc. The relative value of these metrics is different for different applications, so we end up with many different types of batteries being used.

Grid level batteries have another very important metric. The actual possibility of buying a particular types of batteries from friendly nations. Simpler technologies like this CO2 battery have a huge advantage here.

[1] https://en.wikipedia.org/wiki/List_of_battery_types

pfdietz 20 hours ago||
Of course it's true for batteries. There's a huge number of potential battery types, most of which never make it out of the lab, never mind to market. Most on your list there are in are in tiny niches.

To steelman the point you're making: perhaps the short term storage niche will fracture into smaller niches, in which different technologies could coexist. This also happens in ecology. For example, in one simple experiment with bacteria, it was found two species coexisted, but on closer examination it was found one species persisted in the top of the flasks, the other in the bottom.

perlgeek 19 hours ago|||
The definition of "market niche" must do too much work for my liking to make this true.

For example, for the market niche "getting people from one location to another" there are quite many technologies, like walking, bicycles, scooters, cars, trains, ships, airplanes, helicopters etc., none of them evolved as a clear winner that displaced the others.

You might say, that's a whole market, not just a market niche, but it's also a niche of the larger transportation market.

When we look at something like grid-scale energy storage, how do we know if it's a winner-takes-all niche? Maybe constraints such as availability of space, availability of funding, weather, climate, grid demands etc. create sub-niches with their own winners. Or maybe not, but how can we known?

kumarvvr 1 day ago|||
> What we need is a storage technology with a duration of months

Actually, having expandable, highly re-usable tech like this is much better when the capacities are in terms of hours.

This storage, combined with say 2.5x solar panel installation, could essentially provide power at 1x day and night.

pfdietz 1 day ago||
Yes, and we have that. It's called Li-ion batteries.
kumarvvr 1 day ago||
They are good for about 1000 cycles.

This system can run for decades.

pfdietz 1 day ago|||
Utility-scale Li-ion batteries are good for an order of magnitude more than that.

"LFP chemistry offers a considerably longer cycle life than other lithium-ion chemistries. Under most conditions, it supports more than 3,000 cycles; under optimal conditions, more than 10,000 cycles."

https://en.wikipedia.org/wiki/Lithium_iron_phosphate_battery...

kumarvvr 1 day ago||
https://iopscience.iop.org/article/10.1149/1945-7111/abae37/...

This is the paper that claims 10,000 cycles under optimal conditions.

But if you read it, they measure Equivalent Full Cycles, and it seems that implies 10000 cycles at partial discharge, not full discharge.

The paper calculates everything at nominal discharge upto 80%. Meaning, the installed capacity has to be 25% more than paper value, leading to increased costs.

Add to that, batteries are complex to manufacture, degrade, lose capacity, etc. You need high level of quality control to actually ensure you are getting good batteries. This means, the cost of QA and expertise increases. They are costly to replace, even at an avg of 3000 cycles (roughly 10 years). Bad cells in one batch accelerate degradation and are difficult to trace out. Batteries operate best at low temperatures, so the numbers may vary based on installed location and climatic conditions.

A turbine and co2 compressor system is dead simple to manufacture, control and maintain. A simple PLC system and some automation can make them run quite well. Manufacturing complexity is low, as there are tried and tested tech. Basically piping, valves, turbines and generators. These things can be reliably run for 30 to 40 years. Meaning, the economics and cost efficiency is wildly different.

With such simplicity, they can be deployed across the world, especially in places like Africa, middle east, etc.

On the whole, batteries are not explicitly superior as such. There are pros and cons on both sides.

pfdietz 1 day ago|||
3000 is still 3x your number.

In evaluating the importance of this, you need to consider not only the time value of money, but also what one might call the "time value of technology". Does it make sense to make the technology long lived when it's improving so quickly? Or do you just replace it in a decade when things are much cheaper? Was "this PC will last 20 years!" ever a selling point?

When evaluating these technologies, you have to look at not just what they cost now, but how rapidly the cost is improving. Batteries are likely improving more quickly than turbines and heat exchangers.

adrianN 22 hours ago|||
You can buy batteries for your home solar systems with ten year warranties.
PunchyHamster 1 day ago|||
yes because maintenance is free
2thumbsup 1 day ago|||
A few hours are sometimes enough to start generators when renewable energy supply decreases. Obviously, the more capacity the better, but costs will increase linearly with capacity in most cases.

Pumped-storage hydroelectricity - where it is feasible - is the only kind of energy storage close to "months".

ifwinterco 1 day ago|||
You can store energy for months pretty easily as chemical energy. Just get some hydrogen, then join it to something else, maybe carbon, in the right proportion so it's a liquid at room temperature making it nice and easy to both store and transport.

Wait a minute...

pfdietz 1 day ago||||
The point is that's already a well-served market. These competitors are like alternative semiconductors going up against silicon.
pfdietz 1 day ago|||
Oh: pumped hydro is not a "months" storage technology. The capex per unit of storage capacity is far too high.
newyankee 1 day ago|||
Had heard a lot about flow batteries few years back. I am guessing they are slowly taking off as well, the trial and error that explains their feasibility , need and ability to pay for themselves in a market like ERCOT is the key.

This is one place where I think by 2030 a clear no of options will be established.

PunchyHamster 1 day ago|||
Hell, even week will do a lot, you can start importing energy from areas that have currently better renewables conditions over night, even preemptively for a period of bad weather
aqme28 1 day ago|||
I don't understand. Why is a duration of months preferable? What is the benefit above storing energy beyond say peak-to-peak? I suppose you can flatten out seasonal variation, but that's not nearly as big of a problem.
pfdietz 1 day ago||
To see the importance, go to https://model.energy/

This site finds optimal combinations of solar, wind, batteries, and a long term storage (in this case, hydrogen), using historical weather data, to provide "synthetic baseload". It's a simplified model, but it provides important insights.

Go there, and (for various locations) try it with and without the hydrogen. You'll find that in a place at highish lattitude, like (say) Germany, omitting hydrogen doubles the cost. That's because to either smooth over seasonal variation in solar, or over long period drop out of wind, you need to either greatly overprovision those, or greatly overprovision batteries. Just a little hydrogen reduces the needed overprovisioning of those other things, even with hydrogen's lousy round trip efficiency.

Batteries are still extremely important here, for short duration smoothing. Most stored energy is still going through batteries, so their capex and efficiency is important.

You can also tweak the model to allow a little natural gas, limiting it to some fixed percentage (say, 5%) of total electrical output. This also gets around the problem. But we utimately want to totally get off of natural gas.

I suspect thermal storage will beat out hydrogen, if Standard Thermal's "hot dirt" approach pans out.

openasocket 20 hours ago||
I don’t know much about chemistry, but is there a reason why they are using CO2 as the gas medium instead of something else? I was thinking ambient air would be readily available, and you don’t have to worry about suffocating people if it ruptures. Is CO2 particularly efficient to compress?
belviewreview 1 day ago||
I seem to recall from an article I read about this technology a few years ago that it's efficient partly because when the gas is compressed, they are able to store the heat that is produced, and then later use the stored heat for expanding the gas.
andrewflnr 1 day ago|
That seems important. I wish we knew how. I found an article that did mention the heat was "stored", with no further detail. The animation down on this page suggests it's stored in water somehow: https://energydome.com/co2-battery/
nashashmi 1 day ago||
A better understanding of the science in the system: https://newatlas.com/energy/energy-dome-co2-sardinia/

Similar discussion: https://news.ycombinator.com/item?id=44685067 (162p/153c)

jmward01 1 day ago||
As always, diversity in the energy ecosystem is a huge plus. Time and time again we see that 'one size fits all' is simply not true so I'm a fan of alternative approaches that use completely different principles. This enables the energy ecosystem to keep exploring the space of possibilities efficiently. I hope this continues to be developed.
hn_throwaway_99 1 day ago|
> Time and time again we see that 'one size fits all' is simply not true

Do we though? It feels like we're still in the stage where we're just trying to figure out what the best solution is for grid-scale storage, but once we do figure it out, the most efficient solution will win out over all the others. Yes, there may be some regional variation (e.g. TFA mentions how pumped hydro is great but only makes sense where geography supports it), but overall it feels like the world will eventually narrow things down to a very small number of solutions.

jmward01 1 day ago||
The point I was making isn't that we are or aren't actually narrowing down our options, it is that diversity of options is important. We have artificially limited diversity in our energy ecosystem and the rapid adoption of solar/wind/etc shows that. We could have been here decades ago if we actually encouraged diversity and exploration of alternate energy instead of actively discouraging it. Now that it is impossible to hold wind/solar back they are dominating. We should learn from that and encourage exploring diverse options in storage. Luckily I don't think storage has nearly the pushback that generation has had so I think it will be easier for many options to enter and find their niche.
mark-r 1 day ago||
They never mention what advantage CO2 has over any other gas, like plain air?
oneiric 1 day ago|
The fluid in high pressure storage is a liquid, making the storage much cheaper. Liquid N2 (most of air) would require over 40 times more pressure or cold temperatures. Purifying out CO2 or any gas is generally a negligible cost.
nanomonkey 1 day ago||
I'm curious if this method could be used along with super critical CO2 turbine generators. In other words after extracting the energy stored in compressed CO2, if you could then run it through a heat exchanger to bring it up to super critical temps and pressure and then utilize it as the working fluid in a turbine.
pjc50 1 day ago|
It looks from the diagram that a turbine is the energy extraction mechanism? As you'd expect.
nanomonkey 1 day ago||
Correct, going from cold compressed liquid co2 though. For supercritical CO2 one would then heat up the gas and use it as a working fluid to turn the turbines further.

If you could reuse the same turbine, one could store excess solar/wind energy in the compressed gas form, and then fire up a natural gas or biomass gasification reactor and then feed the heat into the system to produce more electricity on demand.

LikeBeans 23 hours ago||
I wonder how does it compare to hoisting a concrete (or something heavy) block up a pulley system as an energy store? When you need the energy you let it slide down pulling some steel cable that turns a generator, or multiple cables into multiple generators. Or even a cascade of concrete blocks at different heights as a space saver.
sowbug 23 hours ago||
The article does address that.

...and even dangling heavy objects in the air and dropping them. (The creativity devoted to LDES is impressive.) But geologic constraints, economic viability, efficiency, and scalability have hindered the commercialization of these strategies.

cenamus 23 hours ago||
Probably extremely poorly, as that's basically pumped hydro on _tiny_ scale. The amount of mass/water that fits into storage lakes is insane
LikeBeans 16 hours ago||
Good point. I was thinking more about areas without much water and a large field of poles each hoisting several blocks. Sort of wind turbines but without the blades.
rbanffy 1 day ago||
I have one concern: what if the container bursts? CO2 is heavier than air, and a sudden pressure decrease will cool it down further, so it'll hug the ground. What would be a safe distance for the people around the plant to live without the risk of being asphixiated in an accident?
ragebol 1 day ago|
The article mentions > If the worst happens and the dome is punctured, 2,000 tonnes of CO2 will enter the atmosphere. That’s equivalent to the emissions of about 15 round-trip flights between New York and London on a Boeing 777. “It’s negligible compared to the emissions of a coal plant,” Spadacini says. People will also need to stay back 70 meters or more until the air clears, he says.

So: 70 meters

gosub100 1 day ago||
> or more

I guess it just depends on how much oxygen you really need.

euroderf 12 hours ago|
Had to wade thru miles of marketing muck to get to the tech talk.
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